| Round 5 on 2022/10/06 at 15:00 |
| Bo. | 5 | Turkiye-Red | Rtg | - | 6 | Kazakhstan | Rtg | 3½: ½ |
| 1.1 | FM | | 2428 | - | FM | | 2323 | 1 - 0 |
| 1.2 | FM | | 2323 | - | WIM | | 2231 | 1 - 0 |
| 1.3 | FM | | 2299 | - | WIM | | 2188 | 1 - 0 |
| 1.4 | WFM | | 2109 | - | | | 2098 | ½ - ½ |
| Bo. | 1 | Iran | Rtg | - | 3 | India | Rtg | 2 : 2 |
| 2.1 | IM | | 2515 | - | IM | | 2530 | ½ - ½ |
| 2.2 | FM | | 2324 | - | IM | | 2442 | 0 - 1 |
| 2.3 | FM | | 2325 | - | FM | | 2228 | 1 - 0 |
| 2.4 | | | 1925 | - | | | 1808 | ½ - ½ |
| Bo. | 4 | Azerbaijan-1 | Rtg | - | 2 | Uzbekistan-1 | Rtg | 2 : 2 |
| 3.1 | FM | | 2455 | - | IM | | 2441 | ½ - ½ |
| 3.2 | FM | | 2342 | - | FM | | 2367 | 0 - 1 |
| 3.3 | FM | | 2304 | - | | | 2287 | ½ - ½ |
| 3.4 | | | 1810 | - | WFM | | 2078 | 1 - 0 |
| Bo. | 7 | Turkiye-White | Rtg | - | 8 | Cuba | Rtg | 1½:2½ |
| 4.1 | FM | | 2370 | - | FM | | 2315 | ½ - ½ |
| 4.2 | FM | | 2325 | - | | | Gonzalez Soler Leduard Manuel |
| 2251 | 0 - 1 |
| 4.3 | FM | | 2322 | - | | | Hernandez Izquierdo Jose A. |
| 2140 | 1 - 0 |
| 4.4 | | | 1800 | - | | | 1912 | 0 - 1 |
| Bo. | 9 | Turkiye-Anatolia | Rtg | - | 17 | Georgia-1 | Rtg | 3 : 1 |
| 5.1 | FM | | 2320 | - | | | 2012 | 1 - 0 |
| 5.2 | | | 2249 | - | | | 1957 | 1 - 0 |
| 5.3 | CM | | 2223 | - | WFM | | 1814 | 1 - 0 |
| 5.4 | | | 1752 | - | | | 2032 | 0 - 1 |
| Bo. | 19 | Sri Lanka | Rtg | - | 13 | Mongolia | Rtg | 0 : 4 |
| 6.1 | | | 1907 | - | FM | | 2202 | 0 - 1 |
| 6.2 | | | 1987 | - | FM | | 2128 | 0 - 1 |
| 6.3 | | | 1679 | - | FM | | 2200 | 0 - 1 |
| 6.4 | WCM | | Wickramasinghe Minethma Lasandi |
| 1574 | - | | | 1590 | 0 - 1 |
| Bo. | 10 | Azerbaijan-2 | Rtg | - | 23 | Azerbaijan-4 | Rtg | 1 : 3 |
| 7.1 | FM | | 2304 | - | | | 2043 | 0 - 1 |
| 7.2 | | | 2150 | - | | | 1883 | 0 - 1 |
| 7.3 | | | 1731 | - | | | 1664 | 0 - 1 |
| 7.4 | | | 1732 | - | | | 1451 | 1 - 0 |
| Bo. | 16 | Latvia | Rtg | - | 11 | Mexico | Rtg | 1½:2½ |
| 8.1 | | | 1976 | - | | | Montes Orozco Miguel Angel |
| 2051 | ½ - ½ |
| 8.2 | | | 1878 | - | | | Paredes Guzman Francisco Javier |
| 2023 | ½ - ½ |
| 8.3 | | | 1810 | - | | | Zacarias Rodriguez Santiago |
| 2123 | 0 - 1 |
| 8.4 | | | 1625 | - | | | Diaz Bartolo Elizabeth Schahrazad |
| 1666 | ½ - ½ |
| Bo. | 26 | Malaysia | Rtg | - | 12 | Kyrgyzstan | Rtg | 0 : 4 |
| 9.1 | | | 1824 | - | FM | | 2344 | 0 - 1 |
| 9.2 | | | Navaratnam Ishaan Quan Tze |
| 1862 | - | FM | | 2260 | 0 - 1 |
| 9.3 | | | 1428 | - | | | 1940 | 0 - 1 |
| 9.4 | | | Cairel Adrin Rumi Arjuna Malique |
| 1223 | - | | | 1617 | 0 - 1 |
| Bo. | 15 | Bangladesh | Rtg | - | 18 | Uzbekistan-2 | Rtg | ½ :3½ |
| 10.1 | | | 1979 | - | | | 2064 | 0 - 1 |
| 10.2 | | | 1624 | - | WFM | | 2118 | 0 - 1 |
| 10.3 | CM | | 2107 | - | | | 1777 | ½ - ½ |
| 10.4 | CM | | 2001 | - | | | 1552 | 0 - 1 |
| Bo. | 24 | South Africa-1 | Rtg | - | 14 | Moldova | Rtg | ½ :3½ |
| 11.1 | CM | | 2063 | - | | | 2121 | 0 - 1 |
| 11.2 | | | 1687 | - | | | 1974 | ½ - ½ |
| 11.3 | | | 1362 | - | | | 1703 | 0 - 1 |
| 11.4 | | | 1567 | - | | | 1957 | 0 - 1 |
| Bo. | 21 | Canada | Rtg | - | 25 | Azerbaijan-Nakhchivan | Rtg | 2 : 2 |
| 12.1 | CM | | 2154 | - | | | 2125 | 0 - 1 |
| 12.2 | | | 1805 | - | | | 1547 | 1 - 0 |
| 12.3 | | | 1774 | - | | | 1777 | 1 - 0 |
| 12.4 | | | 1649 | - | | | 1578 | 0 - 1 |
| Bo. | 22 | England | Rtg | - | 29 | Hong Kong | Rtg | 2½:1½ |
| 13.1 | | | 1952 | - | | | 1843 | 0 - 1 |
| 13.2 | | | 1871 | - | | | 1766 | ½ - ½ |
| 13.3 | | | 1840 | - | | | 1610 | 1 - 0 |
| 13.4 | | | 1687 | - | | | 0 | 1 - 0 |
| Bo. | 30 | Azerbaijan-Sumgayit Olympic SC | Rtg | - | 20 | Panama | Rtg | 2 : 2 |
| 14.1 | | | 1571 | - | | | Batista Rosas Nicolas Arturo |
| 1941 | ½ - ½ |
| 14.2 | | | 1585 | - | | | Schnell Sebastian Narayana |
| 1847 | 1 - 0 |
| 14.3 | | | 1318 | - | | | Castillo Beitia Ashley Alexandra |
| 1674 | ½ - ½ |
| 14.4 | | | 1034 | - | | | Ibanez Zanetti Sebastian Andres |
| 1433 | 0 - 1 |
| Bo. | 31 | South Africa-3 | Rtg | - | 32 | South Africa-2 | Rtg | ½ :3½ |
| 15.1 | | | 1430 | - | | | 1725 | 0 - 1 |
| 15.2 | | | 1315 | - | | | 1466 | 0 - 1 |
| 15.3 | | | 1168 | - | | | 0 | 0 - 1 |
| 15.4 | | | 1394 | - | | | 1191 | ½ - ½ |
| Bo. | 28 | Lebanon | Rtg | - | 34 | Georgia-2 | Rtg | 4 : 0 |
| 16.1 | | | 1928 | - | | | 0 | 1 - 0 |
| 16.2 | | | 1522 | - | | | 0 | 1 - 0 |
| 16.3 | | | 1553 | - | | | 0 | 1 - 0 |
| 16.4 | | | 1385 | - | | | 0 | 1 - 0 |
| Bo. | 33 | Egypt | Rtg | - | 27 | Azerbaijan-3 | Rtg | 1 : 3 |
| 17.1 | | | 1609 | - | | | 1492 | 0 - 1 |
| 17.2 | | | 1288 | - | WCM | | 1508 | 0 - 1 |
| 17.3 | | | 1503 | - | WCM | | 1356 | 1 - 0 |
| 17.4 | | | 0 | - | | | 1225 | 0 - 1 |